Liquid‐Filling Polydimethylsiloxane Composites with Enhanced Triboelectric Performance for Flexible Nanogenerators

Material functionalization of triboelectric nanogenerators (TENG) plays an important role in TENG's electric performance for sustainable energy harvesting. In this work, a method for improving polydimethylsiloxane (PDMS) composites triboelectric performance has been proposed, via filling high dielectric constant liquid (instead of solids) into PDMS matrix. The improvement is attributed to the high dielectric constant liquid in PDMS matrix that reduced the effective thickness of PDMS and increased the dielectric constant of PDMS composite synchronously. At 50% filling ratio (PDMS‐HD50), the triboelectric performance exhibits an enhancement of 4.5‐fold in output voltage and 3.9‐fold in output current as compared to pure PDMS. The results, besides higher transparency, are superior to the results from traditional solid dielectric constant doping materials like BaTiO₃ nanoparticle in PDMS. This work has proved potentials of dielectric liquid filling materials in fabricating TENGs and could be a guidance for exploring new liquid filling materials.     

基于ARM7的高精度频率计的设计

文章通过对相位重合检测技术的分析，提出了基于此理论并用ARM7作为主控芯片的高精度频率计的设计方法。该设计方法通过捕捉相位之间的重合点，能够有效消除±1个字的计数误差。在此基础上由于ARM7具有32位的处理器内核以及流水线技术，使得频率计的测量速度和精度比传统的使用16位单片机设计的频率计要高很多。本频率计最大测量频率为10MHz。同时本设计采用安捷伦公司生产的恒温晶振10811A作为标准频率，能够有效保证测量精度能够达到10-10量级。为了降低成本，在设计中选用采用ARM7芯片内部的计数器以及用简单的逻辑电路进行设计。由于其测量精度要超过多周期同步测量法，而成本又比模拟内插法和游标法低很多，因此此频率计拥有很广泛的市场前景。     

通风量对菇渣好氧发酵温度时空特性的影响

采用不同通风量进行菇渣与猪粪高温共发酵,研究通风对发酵过程中堆体温度的时空变化的影响。结果表明,通风使堆体温度呈现出明显的梯度效应,不同处理各发酵时期的温度分布均由剖面中部向四周不断降低。高温区域的位置和面积随发酵时间呈动态变化规律,升温期温度在发酵罐中上部积聚,高温分布区类似椭圆形,高温期椭圆面积逐渐向堆体中部扩散和扩大,随后高温面积不断递减并向中下部迁移,降温期堆体各区域温度趋于一致。由等值线的疏密程度可知,温度的空间变异性大体呈现出高温期>第2次高温期>升温期>降温期的规律。结合试验各阶段的温度变化并考虑节能降耗,得出发酵升温期和高温期分别以0.05,0.067m3/(d·m3)进行通风,二次高温期与降温期以0.033 m3/(d·m3)进行通风条件最佳。     

Symmetry Breaking in Monometallic Nanocrystals toward Broadband and Direct Electron Transfer Enhanced Plasmonic Photocatalysis

Metallic nanocrystals manifest themselves as fascinating light absorbers for applications in plasmon-enhanced photocatalysis and solar energy harvesting. The essential challenges lie in harvesting the full-spectrum solar light and harnessing the plasmon-induced hot carriers at the metal–acceptor interface. To this end, a cooperative overpotential and underpotential deposition strategy is proposed to mitigate both the challenges. Specifically, by utilizing both ionic additive and thiol passivator to introduce symmetry-breaking growth over gold icosahedral nanocrystals, the microscopic origin can be attributed to the site-specific nucleation of stacking faults and dislocations. By adopting asymmetric crystal shape and unique surface facets, such nanocrystals attain high activity toward photocatalytic ammonia borane hydrolysis, arising from combined broadband plasmonic properties and enhanced direct transfer of hot electrons across the metal–adsorbate interface.     

An efficient NFEM for optimal control problems governed by a bilinear state equation

In this paper, a nonconforming finite element method (NFEM) is proposed for the constrained optimal control problems (OCPs) governed by a bilinear state equation. The state and adjoint state are approximated by the nonconforming $E{Q}_1^{rot}$ element, and the control is approximated by the orthogonal projection through the state and adjoint state. Some superclose and superconvergence properties are obtained by full use of the distinguish characters of this $E{Q}_1^{rot}$ element, such as the interpolation operator equals the Ritz projection, and the consistency error is one order higher than its interpolation error in the broken energy norm. Finally, some numerical results are provided to verify the theoretical analysis.     

基于颜色四通道及空间金字塔的鱼类图像检索

随着计算机视觉技术在海洋水产领域中的应用不断加深，鱼类图像检索在渔业资源调查、鱼类行为学分析等方面发挥了巨大的作用。通过研究发现，鱼类图像的背景信息会对鱼类图像检索造成极大干扰，而且鱼类图像中颜色、纹理、形状等特征由于空间位置信息的缺乏而使检索的准确率不高。为解决以上问题，提出了一种新的基于颜色四通道及空间金字塔的鱼类图像检索算法。首先，提取视觉显著性图将鱼类图像的前景和背景分开，从而减少图像背景对检索的干扰；其次，为了使图像特征包含一定的空间位置信息，利用空间金字塔的理论对图像进行分割，在此基础上，将图像转为HSVG四通道图并提取SURF特征；；最后，得到检索结果。为验证所提算法的有效性，在QUT_fish_data数据集和DLOU_fish_data数据集上对算法的查全率、查准率与经典的HSVG算法和显著性分块算法进行对比：在两个数据集上查准率分别比传统的HSVG算法最多分别提高12%和5%，查全率最多分别提高7%和22%；比传统的显著性分块算法查准率最多分别提高15%和5%，查全率最多分别提高36%和22%；从而证明所提算法是有效的，能有效提升鱼类图像的检索效果。     

化工原理课程思政建设探索与实践

将思想政治教育融入课程教学的各个环节,实现全程育人、全方位育人,是落实立德树人根本任务的重要途径。文章从介绍课程发展史、传承“时钧精神”、践行绿色发展理念、培养哲学思维、探寻科学家事迹、突出中国传统元素、介绍国家重大工程、引入警示性案例等方面入手,探索如何将思政元素融入化工原理课程教学,并通过创新教学内容与方法,提升教学效果和育人成效。教改践行了“价值引领、知识传授、能力培养”三位一体的教育教学理念。     

Hydrogen Production from Catalytic Steam Reforming of Bio-Oils: A Critical Review

In the future, hydrogen will be an important energy carrier and industrial raw material. Catalytic steam reforming of bio-oils is a promising and economically viable technology for hydrogen production. However, during the reforming process, the catalysts are rapidly deactivated due to coke formation and sintering. Thus, maintaining the activity and stability of catalysts is the key issue in this process. Optimized operation conditions could extend the catalyst lifetime by affecting the coke morphology or promoting coke gasification. This article summarizes the recent developments in the field of catalytic steam reforming of bio-oils, focusing on the operation conditions, the properties of the catalysts, and the effects of the catalyst supports. The expected insights into the catalytic steam reforming of bio-oils will provide further guidance for hydrogen production from bio-oils.     

三软煤层沿空留巷矿压显现规律研究

为探究沿空留巷矿压显现规律及支护对策，以河南西部典型三软煤层为研究对象，构建了数值分析模型，模拟了工作面前方和后方一定范围内巷道围岩变形和应力变化规律，得到了工作面后方围岩受采动影响大、范围广，顶板下沉现象明显。基于现场实测，得到了顶板下沉量、底板鼓起量、充填体的变形、实煤体变形等随采动影响的变化规律，监测了锚杆的轴向受载情况。研究发现，巷旁膏体充填与巷道内高强锚杆+W型钢带构成的支护体系，较好地解决了三软煤层回采巷道围岩控制问题，为类似开采条件下沿空留巷的实施提供了理论和实践依据。